Hello guys. Yip its being awhile and I surpose thats because I've being running my bike sucessfully for the last two years without issue. Well, at least until now

. I'm hoping some1 has had a similar experience and can guide me in the right direction

. Here's my problem. On my last outing with the bike I noticed a "tappet" like noise coming from the front left cylinder region which seemed to worsen after warm up (it's closer to the head than the block). The bike also has a slight backfire which also started about two months ago and this started after I accidentally filled the tank with lead replacement fuel. My initial thought was its probably running rich so every chance I got I topped up with unleaded to dilute, but that was about 4-5 tanks ago and I still have the back fire. Anyways, Last night I started the bike up (on choke) and once warm, I checked the temperatures of the exhausts at the closest point to the cylinder head using my laser thermometer and whoa

here's what I found. Front left was at 254 degC, and the other 3 were at about 150-160 degC. So I just switched off and thought of you guys

. Any Ideas?? I doubt the lead replacement issue has anything to do with it, but I thought I'd just add that in seein as thats what started the initial back fire, but it may just be coincidental unless I burnt a valve or something.
Valve clearance?? but would that cause such a discrepancy?
Piston slap?? Oil hole or rings maybe?? rings were mic'ed before installation.
burnt valve/s perhaps?
Carb need balancing??overfueling in that cylinder??
I dunno, just throwing some thoughts out there.
Q, when using choke, does it richen all 4 cylinders or just 1 (perhaps the front left

)? cause also, maybe I checked temp to soon after warm up. I'll retry tonight, but my worry is why such a huge discrepancy, so I'm appreciating all your help and experience and expertese

.
Thanx
Cap